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Portland cement

Portland cement (often referred to as OPC, from Ordinary Portland Cement) is the most common type of cement in general use around the world, because it is a basic ingredient of concrete, mortar, stucco and most non-specialty grout. It is a fine powder produced by grinding Portland cement clinker (more than 90%), a limited amount of calcium sulfate which controls the set time, and up to 5% minor constituents (as allowed by various standards).

As defined by the European Standard EN197.1, "Portland cement clinker is a hydraulic material which shall consist of at least two-thirds by mass of calcium silicates (3CaO.SiO2 and 2CaO.SiO2), the remainder consisting of aluminium- and iron-containing clinker phases and other compounds. The ratio of CaO to SiO2 shall not be less than 2.0. The magnesium content (MgO) shall not exceed 5.0% by mass." (The last two requirements were already set out in the German Standard, issued in 1909).

Portland cement clinker is made by heating, in a kiln, a homogeneous mixture of raw materials to a sintering temperature, which is about 1450 °C for modern cements. The aluminium oxide and iron oxide are present as a flux and contribute little to the strength. For special cements, such as Low Heat (LH) and Sulfate Resistant (SR) types, it is necessary to limit the amount of tricalcium aluminate (3CaO.Al2O3) formed. The major raw material for the clinker-making is usually limestone (CaCO3) mixed with a second material containing clay as source of alumino-silicate. Normally, an impure limestone which contains clay or SiO2 is used. The CaCO3 content of these limestones can be as low as 80%. Second raw materials (materials in the rawmix other than limestone) depend on the purity of the limestone. Some of the second raw materials used are: clay, shale, sand, iron ore, bauxite, fly ash and slag. When a cement kiln is fired by coal, the ash of the coal acts as a secondary raw material.

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History

Portland was developed from so called natural cements made in Britain in the early part of the nineteenth century, and its name is derived from its similarity to Portland stone, a type of building stone that was quarried on the Isle of Portland in Dorset, England.

Joseph Aspdin, a British bricklayer, in 1824 was granted a patent for a process of making a cement which he called Portland cement. His cement was an artificial cement similar in properties to the material known as "Roman Cement" (patented in 1796 by James Parker) and his process was similar to that patented in 1822 and used since 1811 by James Frost who called his cement "British Cement". The name "Portland cement" is also recorded in a directory published in 1823 being associated with a William Lockwood and possibly others.

Aspdin's son William in 1843 made an improved version of this cement and he initially called it "Patent Portland cement" although he had no patent. In 1848 William Aspdin further improved his cement and in 1853 moved to Germany where he was involved in cement making. Many people have claimed to have made the first Portland cement in the modern sense, but it is generally accepted that it was first manufactured by William Aspdin at Northfleet, England in about 1842. The German Government issued a standard on Portland cement in 1878.
Production
TXI cement plant, Midlothian, Texas
Schematic explanation of Portland cement production

There are three fundamental stages in the production of Portland cement:

1. Preparation of the raw mixture
2. Production of the clinker
3. Preparation of the cement

The chemistry of cement is very complex, so cement chemist notation was invented to simplify the formula of common oxides found in cement. This reflects the fact that most of the elements are present in their highest oxidation state, and chemical analyses of cement are expressed as mass percent of these notional oxides.
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Rawmix preparation

A limestone prehomogenization pile being built by a boom stacker
A completed limestone prehomogenization pile

The raw materials for Portland cement production are a mixture (as fine powder in the 'Dry process' or in the form of a slurry in the 'Wet process') of minerals containing calcium oxide, silicon oxide, aluminium oxide, ferric oxide, and magnesium oxide. The raw materials are usually quarried from local rock, which in some places is already practically the desired composition and in other places requires the addition of clay and limestone, as well as iron ore, bauxite or recycled materials. The individual raw materials are first crushed, typically to below 50 mm. In many plants, some or all of the raw materials are then roughly blended in a "prehomogenization pile." The raw materials are next ground together in a rawmill. Silos of individual raw materials are arranged over the feed conveyor belt. Accurately controlled proportions of each material are delivered onto the belt by weigh-feeders. Passing into the rawmill, the mixture is ground to rawmix. The fineness of rawmix is specified in terms of the size of the largest particles, and is usually controlled so that there are less than 5%-15% by mass of particles exceeding 90 μm in diameter. It is important that the rawmix contains no large particles in order to complete the chemical reactions in the kiln, and to ensure the mix is chemically homogenous. In the case of a dry process, the rawmill also dries the raw materials, usually by passing hot exhaust gases from the kiln through the mill, so that the rawmix emerges as a fine powder. This is conveyed to the blending system by conveyor belt or by a powder pump. In the case of wet process, water is added to the rawmill feed, and the mill product is a slurry with moisture content usually in the range 25-45% by mass. This slurry is conveyed to the blending system by conventional liquid pumps.
Rawmix blending

The rawmix is formulated to a very tight chemical specification. Typically, the content of individual components in the rawmix must be controlled within 0.1% or better. Calcium and silicon are present in order to form the strength-producing calcium silicates. Aluminium and iron are used in order to produce liquid ("flux") in the kiln burning zone. The liquid acts as a solvent for the silicate-forming reactions, and allows these to occur at an economically low temperature. Insufficient aluminium and iron lead to difficult burning of the clinker, while excessive amounts lead to low strength due to dilution of the silicates by aluminates and ferrites. Very small changes in calcium content lead to large changes in the ratio of alite to belite in the clinker, and to corresponding changes in the cement's strength-growth characteristics. The relative amounts of each oxide are therefore kept constant in order to maintain steady conditions in the kiln, and to maintain constant product properties. In practice, the rawmix is controlled by frequent chemical analysis (hourly by X-Ray fluorescence analysis, or every three minutes by prompt gamma neutron activation analysis). The analysis data is used to make automatic adjustments to raw material feed rates. Remaining chemical variation is minimized by passing the raw mix through a blending system that homogenizes up to a day's supply of rawmix (15,000 tonnes in the case of a large kiln).

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Formation of clinker

Precalciner kiln
Typical clinker nodules

The raw mixture is heated in a cement kiln, a slowly rotating and sloped cylinder, with temperatures increasing over the length of the cylinder up to a peak temperature of 1400-1450 °C. A complex succession of chemical reactions take place (see cement kiln) as the temperature rises. The peak temperature is regulated so that the product contains sintered but not fused lumps. Sintering consists of the melting of 25-30% of the mass of the material. The resulting liquid draws the remaining solid particles together by surface tension, and acts as a solvent for the final chemical reaction in which alite is formed. Too low a temperature causes insufficient sintering and incomplete reaction, but too high a temperature results in a molten mass or glass, destruction of the kiln lining, and waste of fuel. When all goes to plan, the resulting material is clinker. On cooling, it is conveyed to storage. Some effort is usually made to blend the clinker, because although the chemistry of the rawmix may have been tightly controlled, the kiln process potentially introduces new sources of chemical variability. The clinker can be stored for a number of years before use. Prolonged exposure to water decreases the reactivity of cement produced from weathered clinker.

The enthalpy of formation of clinker from calcium carbonate and clay minerals is ~1700 kJ/kg. However, because of heat loss during production, actual values can be much higher. The high energy requirements and the release of significant amounts of carbon dioxide makes cement production a concern for global warming. See "Environmental effects" below.

Cement grinding

A 10 MW cement mill, producing cement at 270 tonnes per hour

In order to achieve the desired setting qualities in the finished product, a quantity (2-8%, but typically 5%) of calcium sulfate (usually gypsum or anhydrite) is added to the clinker and the mixture is finely ground to form the finished cement powder. This is achieved in a cement mill. The grinding process is controlled to obtain a powder with a broad particle size range, in which typically 15% by mass consists of particles below 5 μm diameter, and 5% of particles above 45 μm. The measure of fineness usually used is the "specific surface", which is the total particle surface area of a unit mass of cement. The rate of initial reaction (up to 24 hours) of the cement on addition of water is directly proportional to the specific surface. Typical values are 320-380 m2·kg−1 for general purpose cements, and 450-650 m2·kg−1 for "rapid hardening" cements. The cement is conveyed by belt or powder pump to a silo for storage. Cement plants normally have sufficient silo space for 1–20 weeks production, depending upon local demand cycles. The cement is delivered to end-users either in bags or as bulk powder blown from a pressure vehicle into the customer's silo. In developed countries, 80% or more of cement is delivered in bulk, and many cement plants have no bag-packing facility. In poor countries, bags are the normal mode of delivery.

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Brick

A brick is a block of ceramic material used in masonry construction, usually laid using mortar.
History
The Roman Constantine Basilica in Trier, Germany, built in the 4th century with fired bricks as audience hall for Constantine I

The oldest shaped bricks found date back to 7,500 B.C.[citation needed] They have been found in Çayönü, in the upper Tigris region, and in south east Anatolia close to Diyarbakir. Other more recent findings, dated between 7,000 and 6,395 B.C., come from Jericho and Catal Hüyük. From archaeological evidence, the inven­tion of the fired brick (as opposed to the consid­erably earlier sun-dried mud brick) is believed to have arisen in about the third millennium BC. Being much more resistant to cold and moist weather conditions, brick enabled the construction of permanent buildings in regions where the harsher climate precluded the use of mud bricks. Bricks have the added warmth benefit of storing heat energy from the sun during the day and continuing to release heat after sunset.

Examples of the civilizations who used mudbrick are the ancient Egyptians and the Indus Valley Civilization, where it was used exclusively. In particular, it is evident from the ruins of Buhen, Mohenjo-daro and Harappa.
The ancient Jetavanaramaya stupa in Anuradhapura, Sri Lanka is one of the largest brick structures in the world
The world's highest brick tower of St. Martin's Church in Landshut, Germany, completed in 1500
Malbork Castle, former Ordensburg of the Teutonic Order - biggest brick castle in the world

In Sumerian times offerings of food and drink were presented to "the Bone god," who was "rep­resented in the ritual by the first brick."[citation needed] More recently, mortar for the foundations of the Hagia Sophia in Istanbul was mixed with "a broth of barley and bark of elm" and sacred relics, accom­panied by prayers, placed between every 12 bricks.[citation needed]

The Romans made use of fired bricks, and the Roman legions, which operated mobile kilns, introduced bricks to many parts of the empire. Roman bricks are often stamped with the mark of the legion that supervised its production. The use of bricks in Southern and Western Germany, for example, can be traced back to traditions already described by the Roman architect Vitruvius.

In pre-modern China, brick-making was the job of a lowly and unskilled artisan, but a kiln master was respected as a step above the latter.[1] Early descriptions of the production process and glazing techniques used for bricks can be found in the Song Dynasty carpenter's manual Yingzao Fashi, published in 1103 by the government official Li Jie, who was put in charge of overseeing public works for the central government's construction agency. The historian Timothy Brook writes of the production process in Ming Dynasty China (aided with visual illustrations from the Tiangong Kaiwu encyclopedic text published in 1637):
The brickwork of Shebeli Tower in Iran displays 12th century craftsmanship

...the kilnmaster had to make sure that the temperature inside the kiln stayed at a level that caused the clay to shimmer with the colour of molten gold or silver. He also had to know when to quench the kiln with water so as to produce the surface glaze. To anonymous laborers fell the less skilled stages of brick production: mixing clay and water, driving oxen over the mixture to trample it into a thick paste, scooping the paste into standardized wooden frames (to produce a brick roughly 42 cm long, 20 cm wide, and 10 cm thick), smoothing the surfaces with a wire-strung bow, removing them from the frames, printing the fronts and backs with stamps that indicated where the bricks came from and who made them, loading the kilns with fuel (likelier wood than coal), stacking the bricks in the kiln, removing them to cool while the kilns were still hot, and bundling them into pallets for transportation. It was hot, filthy work.

The idea of signing the worker's name on the brick and the place where it was made was not new to the Ming era and had little or nothing to do with vanity.[3] As far back as the Qin Dynasty (221 BC–206 BC), the government required blacksmiths and weapon-makers to engrave their names onto weapons in order to trace the weapon back to them, lest their weapons should prove to be of a lower quality than the standard required by the government.

In the 12th century, bricks from Northern Italy were re-introduced to Northern Germany, where an independent tradition evolved. It culminated in the so-called brick Gothic, a reduced style of Gothic architecture that flourished in Northern Europe, especially in the regions around the Baltic Sea which are without natural rock resources. Brick Gothic buildings, which are built almost exclusively of bricks, are to be found in Denmark, Germany, Poland, and Russia.

During the Renaissance and the Baroque, visible brick walls were unpopular and the brickwork was often covered with plaster. It was only during the mid-18th century that visible brick walls regained some degree of popularity, as illustrated by the Dutch Quarter of Potsdam, for example.
Chile house in Hamburg, Germany

The transport in bulk of building materials such as sponge over long distances was rare before the age of canals, railways, roads and heavy goods vehicles. Before this time bricks were generally made close to their point of intended use. It has been estimated that in England in the eighteenth century carrying bricks by horse and cart for ten miles (16 km) over the poor roads then existing could more than double their price.[citation needed]

Bricks were often used, even in areas where stone was available, for reasons of speed and economy. The buildings of the Industrial Revolution in Britain were largely constructed of brick and timber due to the demand created. During the building boom of the nineteenth century in the eastern seaboard cities of Boston and New York, for example, locally made bricks were often used in construction in preference to the brownstones of New Jersey and Connecticut for these reasons.

The trend of building upwards for offices that emerged towards the beginning of the 19th century displaced brick in favour of cast and wrought iron and later steel and concrete. Some early 'skyscrapers' were made in masonry, and demonstrated the limitations of the material - for example, the Monadnock Building in Chicago (opened in 1896) is masonry and just seventeen stories high, the ground walls are almost 6 feet (1.8 m) thick, clearly building any higher would lead to excessive loss of internal floor space on the lower floors. Brick was revived for high structures in the 1950s following work by the Swiss Federal Institute of Technology and the Building Research Establishment in Watford, UK. This method produced eighteen story structures with bearing walls no thicker than a single brick (150–225 mm). This potential has not been fully developed because of the ease and speed in building with other materials, in the late-20th century brick was confined to low- or medium-rise structures or as a thin decorative cladding over concrete-and-steel buildings or for internal non-load bearing walls.

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Methods of manufacture
Brick making at the beginning of the 20th century.

Bricks may be made from clay, shale, soft slate, calcium silicate, concrete, or shaped from quarried stone.

Clay is the most common material, with modern clay bricks formed in one of three processes - soft mud, dry press, or extruded.

In 2007 a new type of brick was invented, based on fly ash, a by-product of coal power plants.
Mud bricks

The soft mud method is the most common, as it is the most economical. It starts with the raw clay, preferably in a mix with 25-30% sand to reduce shrinkage. The clay is first ground and mixed with water to the desired consistency. The clay is then pressed into steel moulds with a hydraulic press. The shaped clay is then fired ("burned") at 900-1000 °C to achieve strength.
Rail kilns
Xhosa brickmaker at kiln near Ngcobo in the former Transkei in 2007.

In modern brickworks, this is usually done in a continuously fired tunnel kiln, in which the bricks move slowly through the kiln on conveyors, rails, or kiln cars to achieve consistency for all bricks. The bricks often have added lime, ash, and organic matter to speed the burning.
Bull's Trench Kilns

In India, brick making is typically a manual process. The most common type of brick kiln in use there are Bull's Trench Kiln (BTK), based on a design developed by British engineer W. Bull in the late nineteenth century.

An oval or circular trench, 6-9 meters wide, 2-2.5 meters deep, and 100-150 meters in circumference, is dug. A tall exhaust chimney is constructed in the centre. Half or more of the trench is filled with "green" (unfired) bricks which are stacked in an open lattice pattern to allow airflow. The lattice is capped with a roofing layer of finished brick.

In operation, new green bricks, along with roofing bricks, are stacked at one end of the brick pile; cooled finished bricks are removed from the other end for transport. In the middle the brick workers create a firing zone by dropping fuel (coal, [wood], oil, debris, etc) through access holes in the roof above the trench.
West face of Roskilde Cathedral in Roskilde, Denmark.

The advantage of the BTK design is a much greater energy efficiency compared with clamp or scove kilns. Sheet metal or boards are used to route the airflow through the brick lattice so that fresh air flows first through the recently burned bricks, heating the air, then through the active burning zone. The air continues through the green brick zone (pre-heating and drying them), and finally out the chimney where the rising gases create suction which pulls air through the system. The reuse of heated air yields savings in fuel cost.

As with the rail process above, the BTK process is continuous. A half dozen laborers working around the clock can fire approximately 15,000-25,000 bricks a day. Unlike the rail process, in the BTK process the bricks do not move. Instead, the locations at which the bricks are loaded, fired, and unloaded gradually rotate through the trench.
Dry pressed bricks

The dry press method is similar to mud brick but starts with a much thicker clay mix, so it forms more accurate, sharper-edged bricks. The greater force in pressing and the longer burn make this method more expensive.
Extruded bricks

With extruded bricks the clay is mixed with 10-15% water (stiff extrusion) or 20-25% water (soft extrusion). This is forced through a die to create a long cable of material of the proper width and depth. This is then cut into bricks of the desired length by a wall of wires. Most structural bricks are made by this method, as hard dense bricks result, and holes or other perforations can be produced by the die. The introduction of holes reduces the needed volume of clay through the whole process, with the consequent reduction in cost. The bricks are lighter and easier to handle, and have thermal properties different from solid bricks. The cut bricks are hardened by drying for between 20 and 40 hours at 50-150 °C before being fired. The heat for drying is often waste heat from the kiln.

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Calcium silicate bricks

The raw materials for calcium silicate bricks include lime mixed with quartz, crushed flint or crushed siliceous rock together with mineral colourants. The materials are mixed and left until the lime is completely hydrated, the mixture is then pressed into moulds and cured in an autoclave for two or three hours to speed the chemical hardening. The finished bricks are very accurate and uniform, although the sharp arrises need careful handling to avoid damage to brick (and brick-layer). The bricks can be made in a variety of colours, white is common but pastel shades can be achieved.

It is very common in Sweden, especially in houses built or renovated in the '70s. Here it is referred to as "Mexitegel" (en: Mexi[can] Bricks).
Influence on fired colour

The fired colour of clay bricks is influenced by the chemical and mineral content of raw materials, the firing temperature and the atmosphere in the kiln. For example pink coloured bricks are the result of a high iron content, white or yellow bricks have a higher lime content. Most bricks burn to various red hues, if the temperature is increased the colour moves through dark red, purple and then to brown or grey at around 1,300 °C (2,372 °F). Calcium silicate bricks have a wider range of shades and colours, depending on the colourants used. The names of bricks may reflect their origin and colour, such as London Red and Cambridgeshire White.

Bricks formed from concrete are usually termed blocks, and are typically pale grey in colour. They are made from a dry, small aggregate concrete which is formed in steel moulds by vibration and compaction in either an "egglayer" or static machine. The finished blocks are cured rather than fired using low-pressure steam. Concrete blocks are manufactured in a much wider range of shapes and sizes than clay bricks and are also available with a wider range of face treatments - a number of which are to simulate the appearance of clay bricks.

An impervious and ornamental surface may be laid on brick either by salt glazing, in which salt is added during the burning process, or by the use of a "slip," which is a glaze material into which the bricks are dipped. Subsequent reheating in the kiln fuses the slip into a glazed surface integral with the brick base.

Natural stone bricks are of limited modern utility, due to their enormous comparative mass, the consequent foundation needs, and the time-consuming and skilled labour needed in their construction and laying. They are very durable and considered more handsome than clay bricks by some. Only a few stones are suitable for bricks. Common materials are granite, limestone and sandstone. Other stones may be used (e.g. marble, slate, quartzite, etc.) but these tend to be limited to a particular locality.

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Wood

Wood is an organic material; in the strict sense wood is produced as secondary xylem in the stems of trees (and other woody plants). In a living tree it transfers water and nutrients to the leaves and other growing tissues, and has a support function, enabling woody plants to reach large sizes or to stand up for themselves. However, wood may also refer to other plant materials with comparable properties, and to material engineered from wood, or wood chips or fibre.

People have used wood for millennia for many purposes, primarily as a fuel or as a construction material for making houses, tools, weapons, furniture, packaging, artworks, and paper. Wood can be dated by carbon dating and in some species by dendrochronology to make inferences about when a wooden object was created. The year-to-year variation in tree-ring widths and isotopic abundances gives clues to the prevailing climate at that time.
Wood, in the strict sense, is yielded by trees, which increase in diameter by the formation, between the existing wood and the inner bark, of new woody layers which envelop the entire stem, living branches, and roots. Technically this is known as secondary growth; it is the result of cell division in the vascular cambium, a lateral meristem, and subsequent expansion of the new cells.
Growth rings

Where there are clear seasons, growth can occur in a discrete annual or seasonal pattern, leading to growth rings; these can usually be most clearly seen on the end of a log, but are also visible on the other surfaces. If these seasons are annual these growth rings are referred to as annual rings. Where there is no seasonal difference growth rings are likely to be indistinct or absent.

If there are differences within a growth ring, then the part of a growth ring nearest the centre of the tree, and formed early in the growing season when growth is rapid, is usually composed of wider elements. It is usually lighter in colour than that near the outer portion of the ring, and is known as earlywood or springwood. The outer portion formed later in the season is then known as the latewood or summerwood. However, there are major differences, depending on the kind of wood (see below).


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Knots
A knot on a tree at the Garden of the Gods public park in Colorado Springs, Colorado (October 2006).

A knot is a particular type of imperfection in a piece of wood; it will affect the technical properties of the wood, usually for the worse, but may be exploited for artistic effect. In a longitudinally-sawn plank, a knot will appear as a roughly circular "solid" (usually darker) piece of wood around which the grain of the rest of the wood "flows" (parts and rejoins). Within a knot, the direction of the wood (grain direction) is up to 90 degrees different from the grain direction of the regular wood.

In the tree a knot is either the base of a side branch or a dormant bud. A knot (when the base of a side branch) is conical in shape (hence the roughly circular cross-section) with the tip at the point in stem diameter at which the plant's cambium was located when the branch formed as a bud.

During the development of a tree, the lower limbs often die, but may persist for a time, sometimes years. Subsequent layers of growth of the attaching stem are no longer intimately joined with the dead limb, but are grown around it. Hence, dead branches produce knots which are not attached, and likely to drop out after the tree has been sawn into boards.

In grading lumber and structural timber, knots are classified according to their form, size, soundness, and the firmness with which they are held in place. This firmness is affected by, among other factors, the length of time for which the branch was dead while the attaching stem continued to grow.

Knots materially affect cracking (known in the US as checking, and the UK as shakes) and warping, ease in working, and cleavability of timber. They are defects which weaken timber and lower its value for structural purposes where strength is an important consideration. The weakening effect is much more serious when timber is subjected to forces perpendicular to the grain and/or tension than where under load along the grain and/or compression. The extent to which knots affect the strength of a beam depends upon their position, size, number, and condition. A knot on the upper side is compressed, while one on the lower side is subjected to tension. If there is a season check in the knot, as is often the case, it will offer little resistance to this tensile stress. Small knots, however, may be located along the neutral plane of a beam and increase the strength by preventing longitudinal shearing. Knots in a board or plank are least injurious when they extend through it at right angles to its broadest surface. Knots which occur near the ends of a beam do not weaken it. Sound knots which occur in the central portion one-fourth the height of the beam from either edge are not serious defects.

Knots do not necessarily influence the stiffness of structural timber, this will depend on the size and location. Stiffness and elastic strength are more dependent upon the sound wood than upon localised defects. The breaking strength is very susceptible to defects. Sound knots do not weaken wood when subject to compression parallel to the grain.

In some decorative applications, to add visual interest, wood with knots may be preferred.

The traditional style of playing the Basque xylophon txalaparta involves hitting the right knots to obtain different tones (colours).

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Heartwood and sapwood
A section of a Yew branch showing 27 annual growth rings, pale sapwood and dark heartwood, and pith (centre dark spot). The dark radial lines are small knots.

Heartwood is wood that has become more resistant to decay as a result of deposition of chemical substances (a genetically programmed process). Once heartwood formation is complete, the heartwood is dead. Some uncertainty still exists as to whether heartwood is truly dead, as it can still chemically react to decay organisms, but only once (Shigo 1986, 54).

Usually heartwood looks different; in that case it can be seen on a cross-section, usually following the growth rings in shape. Heartwood may (or may not) be much darker than living wood. It may (or may not) be sharply distinct from the sapwood. However, other processes, such as decay, can discolour wood, even in woody plants that do not form heartwood, with a similar colour difference, which may lead to confusion.

Sapwood is the younger, outermost wood; in the growing tree it is living wood, and its principal functions are to conduct water from the roots to the leaves and to store up and give back according to the season the reserves prepared in the leaves. However, by the time they become competent to conduct water, all xylem tracheids and vessels have lost their cytoplasm and the cells are therefore functionally dead. All wood in a tree is first formed as sapwood. The more leaves a tree bears and the more vigorous its growth, the larger the volume of sapwood required. Hence trees making rapid growth in the open have thicker sapwood for their size than trees of the same species growing in dense forests. Sometimes trees (of species that do form heartwood) grown in the open may become of considerable size, 30 cm or more in diameter, before any heartwood begins to form, for example, in second-growth hickory, or open-grown pines.

The term heartwood derives solely from its position and not from any vital importance to the tree. This is evidenced by the fact that a tree can thrive with its heart completely decayed. Some species begin to form heartwood very early in life, so having only a thin layer of live sapwood, while in others the change comes slowly. Thin sapwood is characteristic of such species as chestnut, black locust, mulberry, osage-orange, and sassafras, while in maple, ash, hickory, hackberry, beech, and pine, thick sapwood is the rule. Others never form heartwood.

There is no definite relation between the annual rings of growth and the amount of sapwood. Within the same species the cross-sectional area of the sapwood is very roughly proportional to the size of the crown of the tree. If the rings are narrow, more of them are required than where they are wide. As the tree gets larger, the sapwood must necessarily become thinner or increase materially in volume. Sapwood is thicker in the upper portion of the trunk of a tree than near the base, because the age and the diameter of the upper sections are less.

When a tree is very young it is covered with limbs almost, if not entirely, to the ground, but as it grows older some or all of them will eventually die and are either broken off or fall off. Subsequent growth of wood may completely conceal the stubs which will however remain as knots. No matter how smooth and clear a log is on the outside, it is more or less knotty near the middle. Consequently the sapwood of an old tree, and particularly of a forest-grown tree, will be freer from knots than the inner heartwood. Since in most uses of wood, knots are defects that weaken the timber and interfere with its ease of working and other properties, it follows that a given piece of sapwood, because of its position in the tree, may well be stronger than a piece of heartwood from the same tree.

It is remarkable that the inner heartwood of old trees remains as sound as it usually does, since in many cases it is hundreds, and in a few instances thousands, of years old. Every broken limb or root, or deep wound from fire, insects, or falling timber, may afford an entrance for decay, which, once started, may penetrate to all parts of the trunk. The larvae of many insects bore into the trees and their tunnels remain indefinitely as sources of weakness. Whatever advantages, however, that sapwood may have in this connection are due solely to its relative age and position.

If a tree grows all its life in the open and the conditions of soil and site remain unchanged, it will make its most rapid growth in youth, and gradually decline. The annual rings of growth are for many years quite wide, but later they become narrower and narrower. Since each succeeding ring is laid down on the outside of the wood previously formed, it follows that unless a tree materially increases its production of wood from year to year, the rings must necessarily become thinner as the trunk gets wider. As a tree reaches maturity its crown becomes more open and the annual wood production is lessened, thereby reducing still more the width of the growth rings. In the case of forest-grown trees so much depends upon the competition of the trees in their struggle for light and nourishment that periods of rapid and slow growth may alternate. Some trees, such as southern oaks, maintain the same width of ring for hundreds of years. Upon the whole, however, as a tree gets larger in diameter the width of the growth rings decreases.

Different pieces of wood cut from a large tree may differ decidedly, particularly if the tree is big and mature. In some trees, the wood laid on late in the life of a tree is softer, lighter, weaker, and more even-textured than that produced earlier, but in other trees, the reverse applies. This may or may not correspond to heartwood and sapwood. In a large log the sapwood, because of the time in the life of the tree when it was grown, may be inferior in hardness, strength, and toughness to equally sound heartwood from the same log. In a smaller tree, the reverse may be true.

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Colour


In species which show a distinct difference between heartwood and sapwood the natural colour of heartwood is usually darker than that of the sapwood, and very frequently the contrast is conspicuous (see section of yew log above). This is produced by deposits in the heartwood of chemical substances, so that a dramatic colour difference does not mean a dramatic difference in the mechanical properties of heartwood and sapwood, although there may be a dramatic chemical difference.

Some experiments on very resinous Longleaf Pine specimens indicate an increase in strength, due to the resin which increases the strength when dry. Such resin-saturated heartwood is called "fat lighter". Structures built of fat lighter are almost impervious to rot and termites; however they are very flammable. Stumps of old longleaf pines are often dug, split into small pieces and sold as kindling for fires. Stumps thus dug may actually remain a century or more since being cut. Spruce impregnated with crude resin and dried is also greatly increased in strength thereby.
The wood of Coast Redwood is distinctively red in colour

Since the latewood of a growth ring is usually darker in colour than the earlywood, this fact may be used in judging the density, and therefore the hardness and strength of the material. This is particularly the case with coniferous woods. In ring-porous woods the vessels of the early wood not infrequently appear on a finished surface as darker than the denser latewood, though on cross sections of heartwood the reverse is commonly true. Except in the manner just stated the colour of wood is no indication of strength.

Abnormal discolouration of wood often denotes a diseased condition, indicating unsoundness. The black check in western hemlock is the result of insect attacks. The reddish-brown streaks so common in hickory and certain other woods are mostly the result of injury by birds. The discolouration is merely an indication of an injury, and in all probability does not of itself affect the properties of the wood. Certain rot-producing fungi impart to wood characteristic colours which thus become symptomatic of weakness; however an attractive effect known as spalting produced by this process is often considered a desirable characteristic. Ordinary sap-staining is due to fungous growth, but does not necessarily produce a weakening effect.

Ferroconcrete

Reinforced concrete is concrete in which steel reinforcement bars ("rebars"), plates or fibers have been incorporated to strengthen a material that would otherwise be brittle.
History

Building contractor François Coignet was the first to use iron-reinforced concrete as a technique for constructing building structures when he built Parisian houses in the 1850s. His own house at 72 rue Charles-Michels in Paris, built in 1862 still stands. The German company Wayss & Freitag was formed in 1875, with A.G. Wayss publishing a book on reinforced concrete in 1887. Their major competitor in Europe was the firm of François Hennebique, set up in 1892.

The first recorded residence built of reinforced concrete in Scotland was Glencripesdale House, built in 1874, which was the 28 bedroom castle which was the main feature of the 35,000 acre Glencripesdale Estate.

The first entirely reinforced concrete fully-framed building in Britain was the flour mill built for Weaver and Co in Swansea in 1897. Designed by Hennebique, the local agent was Louis Gustave Mouchel, the French Consul in Briton Ferry.

A reinforced concrete system was patented in the United States by Thaddeus Hyatt in 1878. The first reinforced concrete building constructed in the United States was the Pacific Coast Borax Company's refinery in Alameda, California, built in 1893.
Use in construction

Concrete is reinforced to give it extra tensile strength; without reinforcement, many concrete buildings would not have been possible.

Reinforced concrete can encompass many types of structures and components, including slabs, walls, beams, columns, foundations, frames and more.

Reinforced concrete can be classified as precast or cast in-situ concrete.

Much of the focus on reinforcing concrete is placed on floor systems. Designing and implementing the most efficient floor system is key to creating optimal building structures. Small changes in the design of a floor system can have significant impact on material costs, construction schedule, ultimate strength, operating costs, occupancy levels and end use of a building.



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Behavior of reinforced concrete
Materials


Concrete is a mixture of cement (usually Portland cement) and stone aggregate. When mixed with a small amount of water, the cement hydrates form microscopic opaque crystal lattices encapsulating and locking the aggregate into a rigid structure. Typical concrete mixes have high resistance to compressive stresses (about 4,000 psi (28 MPa)); however, any appreciable tension (e.g. due to bending) will break the microscopic rigid lattice resulting in cracking and separation of the concrete. For this reason, typical non-reinforced concrete must be well supported to prevent the development of tension.

If a material with high strength in tension, such as steel, is placed in concrete, then the composite material, reinforced concrete, resists compression but also bending, and other direct tensile actions. A reinforced concrete section where the concrete resists the compression and steel resists the tension can be made into almost any shape and size for the construction industry.
Key characteristics

Three physical characteristics give reinforced concrete its special properties. First, the coefficient of thermal expansion of concrete is similar to that of steel, eliminating internal stresses due to differences in thermal expansion or contraction. Second, when the cement paste within the concrete hardens this conforms to the surface details of the steel, permitting any stress to be transmitted efficiently between the different materials. Usually steel bars are roughened or corrugated to further improve the bond or cohesion between the concrete and steel. Third, the alkaline chemical environment provided by calcium carbonate (lime) causes a passivating film to form on the surface of the steel, making it much more resistant to corrosion than it would be in neutral or acidic conditions.

The relative cross-sectional area of steel required for typical reinforced concrete is usually quite small and varies from 1% for most beams and slabs to 6% for some columns. Reinforcing bars are normally round in cross-section and vary in diameter. Reinforced concrete structures sometimes have provisions such as ventilated hollow cores to control their moisture & humidity.
Anti-corrosion measures

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In wet and cold climates, reinforced concrete for roads, bridges, parking structures and other structures that may be exposed to deicing salt may benefit from use of epoxy-coated, hot dip galvanised or stainless steel rebar, although good design and a well-chosen cement mix may provide sufficient protection for many applications. Epoxy coated rebar can easily be identified by the light green colour of its epoxy coating. Hot dip galvanized rebar may be bright or dull grey depending on length of exposure, and stainless rebar exhibits a typical white metallic sheen that is readily distinguishable from carbon steel reinforcing bar. Reference ASTM standard specifications A767 Standard Specification for Hot Dip Galvanised Reinforcing Bars, A775 Standard Specification for Epoxy Coated Steel Reinforcing Bars and A955 Standard Specification for Deformed and Plain Stainless Bars for Concrete Reinforcment

Another, cheaper way or protecting rebars is coating them with zinc phosphate. Zinc phosphate slowly reacts with the corroding agent (e.g., alkali) forming a stable hydroxyapatite layer.

Penetrating sealants typically must be applied some time after curing. Sealants include paint, plastic foams, films and aluminum foil, felts or fabric mats sealed with tar, and layers of bentonite clay, sometimes used to seal roadbeds.

Reinforcement and terminology

A beam bends under bending moment resulting in a small curvature. At the outer face (tensile face) of the curvature the concrete experiences tensile stress while at the inner face (compressive face) it experiences compressive stress.

A "singly-reinforced" concrete means that the concrete element is only reinforced near the tensile face and the reinforcement, called tension steel, is designed to resist the tension.

A "doubly-reinforced" concrete means that beside the tensile reinforcement the concrete element is also reinforced near the compressive face for assisting the concrete to resist compression. The latter reinforcement is called compression steel.

An "under-reinforced" concrete means that the tension capacity of the tensile reinforcement is smaller than the combined compression capacity of the concrete and the compression steel (under-reinforced at tensile face). When the reinforced concrete element is subject to increasing bending moment, the tension steel yields while the concrete does not reach its ultimate failure condition. As the tension steel yields and stretches, an "under-reinforced" concrete also yields in a ductile manner, exhibiting a large deformation and warning before its ultimate failure.

An "over-reinforced" concrete means that the tension capacity of the tension steel is greater than the combined compression capacity of the concrete and the compression steel (over-reinforced at tensile face). An "over-reinforced" element will fail suddenly, when the concrete fails brittle and crashes before yielding of the tension steel. It is however possible to push the design of an "over-reinforced" concrete element to "under-reinforced" concrete element by adding sufficient compression steel. There is however a limit in the quantity of both tension and compression steel for practicality of placement of reinforcement.

Reinforced concrete elements should be designed to be under-reinforced so users of the structure will receive warning of impending collapse.
[edit] Common failure modes of steel reinforced concrete

Reinforced concrete can fail due to inadequate strength, leading to mechanical failure, or due to a reduction in its durability. Corrosion and freeze/thaw cycles may damage poorly designed or constructed reinforced concrete. When rebar corrodes, the oxidation products (rust) expand and tends to flake, cracking the concrete and unbonding the rebar from the concrete. Typical mechanisms leading to durability problems are discussed below.
Mechanical failure

Reinforced concrete can be considered to have failed when significant cracks occur. Cracking of the concrete section can not be prevented however the size of the cracks can be limited and controlled by reinforcement. Cracking defects can allow moisture to penetrate and corrode the reinforcement. This is a serviceability failure in limit state design. Cracking is normally the result of an inadequate quantity of rebar, or rebar spaced at too great a distance. The concrete then cracks either under excess loading, or due to internal effects such as early thermal shrinkage when it cures.

Ultimate failure leading to collapse can be caused by crushing of the concrete matrix, when stresses exceed its strength; by yielding of the rebar; or by bond failure between the concrete and the rebar.

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четверг, 3 декабря 2009 г.

Architecture

Architecture (Latin „architectura“, from the Greek „arkitekton“, ὰρχιτεκτονική – arkhitektonike, from ὰρχι chief or leader and Τεκτονική builder or carpenter) is the art and science of designing buildings and other physical structures.

Architecture is both the process and the product of designing and constructing spaces that reflect and functional, aesthetic and environmental considerations. Architecture requires the use of materials, technology, textures, light, and shadow. As a process, architecture also includes the pragmatic elements of design, such as planning, cost and construction. A wider definition may comprise all design activity from the macro-level (urban design, landscape architecture) to the micro-level (construction details and furniture). In fact, architecture today may refer to the activity of designing any kind of system.

Architectural works are often perceived as cultural and political symbols and as works of art. Historical civilizations are often identified with their surviving architectural achievements.
Architects plan, design and review the construction of buildings and structures for the use of people by the creative organisation of materials and components with consideration to mass, space, form, volume, texture, structure, light, shadow, materials, program, and pragmatic elements such as cost, construction limitations and technology, to achieve an end which is usually functional, economical, practical and often artistic. This distinguishes architecture from engineering design, which has as its primary object the creative manipulation of materials and forms using mathematical and scientific principles. As documentation produced by architects, typically drawings, plans and technical specifications, architecture defines the structure and/or behavior of a building or any other kind of system that is to be or has been constructed.

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Historic treatises
Architectural drawings of details of the Palace of Persepolis, Persia (Iran)

The earliest written work on the subject of architecture is De architectura, by the Roman architect Vitruvius in the early 1st century CE. According to Vitruvius, a good building should satisfy the three principles of firmitatis utilitatis venustatis, which translates roughly as -

* Durability - it should stand up robustly and remain in good condition.
* Utility - it should be useful and function well for the people using it.
* Beauty - it should delight people and raise their spirits.

According to Vitruvius, the architect should strive to fulfill each of these three attributes as well as possible. Leone Battista Alberti, who elaborates on the ideas of Vitruvius in his treatise, De Re Aedificatoria, saw beauty primarily as a matter of proportion, although ornament also played a part. For Alberti, the rules of proportion were those that governed the idealised human figure, the Golden Mean. The most important aspect of beauty was therefore an inherent part of an object, rather than something applied superficially; and was based on universal, recognisable truths. The notion of style in the arts was not developed until the 16th century, with the writing of Vasari.[4] The treatises, by the 18th century, had been translated into Italian, French, Spanish and English.
The Parthenon, Athens, Greece, "the supreme example among architectural sites." (Fletcher).

In the early nineteenth century, Augustus Welby Northmore Pugin wrote Contrasts (1836) that, as the titled suggested, contrasted the modern, industrial world, which he disparaged, with an idealized image of neo-medieval world. Gothic architecture, Pugin believed, was the only “true Christian form of architecture.”

The 19th century English art critic, John Ruskin, in his Seven Lamps of Architecture, published 1849, was much narrower in his view of what constituted architecture. Architecture was the "art which so disposes and adorns the edifices raised by men ... that the sight of them" contributes "to his mental health, power, and pleasure".

For Ruskin, the aesthetic was of overriding significance. His work goes on to state that a building is not truly a work of architecture unless it is in some way "adorned". For Ruskin, a well-constructed, well-proportioned, functional building needed string courses or rustication, at the very least.

On the difference between the ideals of "architecture" and mere "construction", the renowned 20th C. architect Le Corbusier wrote: "You employ stone, wood, and concrete, and with these materials you build houses and palaces: that is construction. Ingenuity is at work. But suddenly you touch my heart, you do me good. I am happy and I say: This is beautiful. That is Architecture".

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Contemporary concepts of architecture

The great 19th century architect of skyscrapers, Louis Sullivan, promoted an overriding precept to architectural design: "Form follows function".

While the notion that structural and aesthetic considerations should be entirely subject to functionality was met with both popularity and skepticism, it had the effect of introducing the concept of "function" in place of Vitruvius "utility". "Function" came to be seen as encompassing all criteria of the use, perception and enjoyment of a building, not only practical but also aesthetic, psychological and cultural.

Nunzia Rondanini stated, "Through its aesthetic dimension architecture goes beyond the functional aspects that it has in common with other human sciences. Through its own particular way of expressing values, architecture can stimulate and influence social life without presuming that, in and of itself, it will promote social development.'

To restrict the meaning of (architectural) formalism to art for art's sake is not only reactionary; it can also be a purposeless quest for perfection or originality which degrades form into a mere instrumentality".

Among the philosophies that have influenced modern architects and their approach to building design are rationalism, empiricism, structuralism, poststructuralism, and phenomenology.

In the late 20th century a new concept was added to those included in the compass of both structure and function, the consideration of sustainability. To satisfy the contemporary ethos a building should be constructed in a manner which is environmentally friendly in terms of the production of its materials, its impact upon the natural and built environment of its surrounding area and the demands that it makes upon non-sustainable power sources for heating, cooling, water and waste management and lighting.

Mounting

Mounting, in computing, is the process of making a file system ready for use by the operating system, typically by reading certain index data structures from storage into memory ahead of time. The term recalls a period in the history of computing when an operator had to physically place (mount) a magnetic tape or hard disk on a spindle before using it.

In Unix-like systems, the mount point is the location in the operating system's directory structure where a mounted file system appears. For example, many modern Linux distributions automatically mount the CD drive as /media/cdrom, so the contents of the CD drive will appear in the /media/cdrom directory.

Normally only the root user can mount a new file system usually using the mount utility, but there are often provisions to allow normal users to mount removable media, such as the pmount package.

The equivalent to mounting in Microsoft Windows is known as mapping a drive. In these systems, all files and directories available to the operating system and its users are to be found relative to the root directory (\), whether those directories are on the same machine or not.

Microsoft's NTFS 3 also supports Volume Mount Points through the use of NTFS reparse points, which allows volumes to be mounted at arbitrary locations in the file system in addition to the standard drive letters (e.g. C:, E:).


In computing, a shared resource or network share is a device or piece of information on a computer that can be remotely accessed from another computer, typically via a local area network or an enterprise Intranet, as if it were a resource in the local machine.

Examples are shared file access (also known as disk sharing and folder sharing), shared printer access (printer sharing), shared scanner access, etc. The shared resource is called a shared disk (also known as mounted disk), shared drive volume, shared folder, shared file, shared document, shared printer or shared scanner.

The term file sharing traditionally means shared file access, especially in the context of operational systems and LAN services, for example in Microsoft Windows documentation[1]. Though, as BitTorrent and similar protocols became available in the early 2000's, the term file sharing increasingly has become associated with peer-to-peer file sharing over the Internet.

Shared file and printer access within a local area network may either be based on a centralized file server or print server, sometimes denoted client-server paradigm, or on a decentralized model, sometimes denoted peer-to-peer network topology or Workgroup (computer networking). In client-server communications, a client process on the local user computer takes the initiative to start the communication, while a server process on the file server or print server remote computer passively waits for requests to start a communication session. In a peer-to-peer network, any computer can be server as well as client.

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Security issues

A network share is typically made accessible to other users by marking any folder or file as shared, or by changing the file system permissions or access rights in the properties of the folder or file. The exact procedure varies by platform. In Windows XP Home Edition operating system, shared files and folders must be placed in the Shared documents folder, typically with the path C:\Documents and Settings\All users\Shared documents.

A network share can become a security liability when access to the shared files is gained (often by devious means) by those who should not have access to them. Network shares relies on a fixed network access, and would consume extensive communication capacity in non-broadband network access. Because of that, shared printer and file access is normally prohibited in firewalls from computers outside the local area network or enterprise Intranet. However, by means of virtual private networks (VPN), shared resources can securely be made available for certified users outside the local network.
[edit] Naming convention and mapping

The share can be accessed by client computers through some naming convention, such as UNC (Universal Naming Convention) used on DOS and Windows PC computers. This implies that a network share can be addressed according to the following:

\\ServerComputerName\ShareName

where ServerComputerName is the WINS name, DNS name or IP address of the server computer, and ShareName may be a folder or file name, or its path. The shared folder can also be given a ShareName that is different from the folder local name at the server side. For example \\server\c$ usually denotes a drive with drive letter C: on a Windows machine.

A shared drive or folder is often mapped at the client PC computer, meaning that it is assigned a drive letter on the local PC computer. For example, the drive letter H: is typically used for the user home directory on a central file server.
[edit] Common file systems and protocols

Shared file and printer access require an operating system on the client that supports access to resources on a server, an operating system on the server that supports access to its resources from a client, and an application layer (in the four or five layer TCP/IP reference model) file sharing protocol and transport layer protocol to provide that shared access. Modern operating systems for personal computers include distributed file systems that support file sharing, while hand-held computing devices sometimes require additional software for shared file access.

The most common such file systems and protocols are:
Primary operating system Application protocol Transport protocol
Mac OS Apple Filing Protocol

The "primary operating system" is the operating system on which the file sharing protocol in question is most commonly used.

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On Microsoft Windows, a network share is provided by the Windows network component "File and Printer Sharing for Microsoft Networks", using Microsoft's SMB (Server Message Block) protocol. Other operating systems might also implement that protocol; for example, Samba is an SMB server running on Unix-like operating systems and some other non-MS-DOS/non-Windows operating systems such as OpenVMS. Samba can be used to create network shares which can be accessed, using SMB, from computers running Microsoft Windows.

Shared resource access can also be implemented with Web-based Distributed Authoring and Versioning (WebDAV).
[edit] Centralized and decentralized architecture

In large enterprise networks, the network share is typically a resource on a centralized file server or printer server, made available to user client computers. In home and small office networks, a decentralized approach is often used, where every user may make their local resources available to others. This approach is sometimes denoted a peer-to-peer network, since the same computer may be used as client as well as server.
[edit] Difference from file transfer

Shared file access should not be confused with file transfer using the file transfer protocol (FTP), or the Bluetooth or IRDA OBject EXchange (OBEX) protocol. Shared access involves automatic synchronization of folder information whenever a folder is changed on the server, and may provide server side file searching, while file transfer is a more rudimentary service.

Shared file access is normally considered as a local area network (LAN) service, while FTP is an Internet service.

Shared file access is transparent to the user, as if it was a resource in the local file system, and supports a multi-user environment. This includes concurrency control or locking of a remote file while a user is editing it, and file system permissions.
[edit] Difference from synchronization

Shared file access involves but should not be confused with file synchronization and other information synchronization. Internet based information synchronization may for example use the SyncML language. Shared file access is based on server side pushing of folder information, and is normally used over an "always on" Internet socket. File synchronization allows the user to be offline from time to time, and is normally based on an agent software that polls synchronized machines at reconnect, and sometimes repeatedly with a certain time interval, to discover differences. Modern operational systems often includes a local cache of remote files, allowing offline access and synchronization when reconnected.

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